TA Instruments

50% SID 50% PCHINA-0028f

29/04/2022 4:11:50 p. m.

Sample name	50% SID 50% PCHINA
Sample notes	 
Experiment notes	
Operator	
Sample density	1,000 g/cm^3
Results file name	50% SID 50% PCHINA
Run number	28 
Results directory	C:\Ta\Data\Ar1500\Ar1500\DIEGO ROA
Experiment was run on	29/04/2022 4:11:50 p. m.

Procedure name	Flow procedure
Procedure notes	

Step name	Conditioning Step 1
Step notes	
Perform step	Yes
Initial temperature	25,0 C
Wait for correct temperature	Yes
Do set temperature	Yes
Perform pre-shear	No
Perform equilibration	Yes
Equilibration duration	0:02:00 hh:mm:ss
Wait for zero velocity	No
Purge gas only	No

Step name	Stepped flow step 1
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000E-3 1/s
End controlled variable	shear rate 0,01000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 2
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,01000 1/s
End controlled variable	shear rate 0,1000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 3
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,1000 1/s
End controlled variable	shear rate 1,000 1/s
Ramp mode	log 
Points per decade	5 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 4
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000 1/s
End controlled variable	shear rate 100,0 1/s
Ramp mode	log 
Points per decade	8 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Conditioning Step 2
Step notes	
Perform step	Yes
Initial temperature	25,0 C
Wait for correct temperature	Yes
Do set temperature	Yes
Perform pre-shear	Yes
Pre-shear variable	10,00 1/s
Pre-shear duration	0:00:10 hh:mm:ss
Motor mode	auto 
Perform equilibration	Yes
Equilibration duration	0:02:00 hh:mm:ss
Wait for zero velocity	No
Purge gas only	No

Step name	Temperature ramp step 1
Step notes	
Perform step	Yes
Ramp type	Temperature ramp
Start temperature	25,0 C
End temperature	90,0 C
Wait for start temperature	Yes
Ramp rate	10,00 C/min
Delay time	0:00:09 hh:mm:ss
Controlled variable	shear rate 10,00 1/s
Motor mode	auto 

Step name	Temperature ramp step 2
Step notes	
Perform step	Yes
Ramp type	Temperature ramp
Start temperature	90,0 C
End temperature	90,0 C
Wait for start temperature	No
Ramp duration	0:05:00 hh:mm:ss
Delay time	0:00:09 hh:mm:ss
Controlled variable	shear rate 10,00 1/s
Motor mode	auto 

Step name	Temperature ramp step 3
Step notes	
Perform step	Yes
Ramp type	Temperature ramp
Start temperature	90,0 C
End temperature	25,0 C
Wait for start temperature	No
Ramp rate	10,00 C/min
Delay time	0:00:09 hh:mm:ss
Controlled variable	shear rate 10,00 1/s
Motor mode	auto 

Step name	Conditioning Step 3
Step notes	
Perform step	Yes
Initial temperature	25,0 C
Wait for correct temperature	Yes
Do set temperature	Yes
Perform pre-shear	Yes
Pre-shear variable	1,000 1/s
Pre-shear duration	0:00:10 hh:mm:ss
Motor mode	auto 
Perform equilibration	Yes
Equilibration duration	0:02:00 hh:mm:ss
Wait for zero velocity	No
Purge gas only	No

Step name	Stepped flow step 5
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000E-3 1/s
End controlled variable	shear rate 0,01000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 6
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,01000 1/s
End controlled variable	shear rate 0,1000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 7
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,1000 1/s
End controlled variable	shear rate 1,000 1/s
Ramp mode	log 
Points per decade	5 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 8
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000 1/s
End controlled variable	shear rate 100,0 1/s
Ramp mode	log 
Points per decade	8 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Post-Experiment Step
Step notes	
Perform step	Yes
Do set temperature	No
Set temperature system idle	No

Geometry name	Starch cell
Geometry notes	Starch cell
Geometry material	High temperature
gap	5500 micro m
Calibration factor	10800 
Gap offset	0 micro m
Geometry inertia	2,224 micro N.m.s^2
Shear rate factor	1,000 
Shear stress factor	10800 1/m^3
Measurement system factor	10800 1/m^3
Fluid density factor	1,000E-15 m^5
Normal force factor	1,000 1/m^2
Backoff distance	1,25E5 micro m

Gap zero mode	Standard
Sample compression	none 
Compression distance	1000,0 micro m
Compression velocity	100,0 micro m/s
Fine velocity	1000,0 micro m/s
Coarse velocity	3000,0 micro m/s
Other velocity	3000,0 micro m/s
Current temperature system	Starch cell
Temperature control	Enabled 
Purge gas only	No
Temperature calibration	Peltier plate - 0 micro m/C
	Water bath - 0 micro m/C
	Torsion oven - plate - 0 micro m/C
	Torsion oven - solid sample - 0 micro m/C
	Peltier concentric cylinders - 0 micro m/C
	None - 0 micro m/C
	Stress relaxation - 0 micro m/C
	Current temperature system - 0 micro m/C
Cooling water temperature	5,0 C
Cooling water range	15,0 C
Bearing friction correction	Yes
Bearing friction	1,222 micro N.m/(rad/s)
Bearing offset	0 micro N.m
Temperature system span and offset	Peltier plate - span 1,0000 , offset 0 C
	Water bath - span 1,0000 , offset 0 C
	Torsion oven - plate - span 1,0000 , offset 0 C
	Torsion oven - solid sample - span 1,0000 , offset 0 C
	Peltier concentric cylinders - span 1,0000 , offset 0 C
	None - span 1,0000 , offset 0 C
	Stress relaxation - span 1,0000 , offset 0 C
	Current temperature system - span 1,0000 , offset 0 C
Bearing mapping type	fast 
Number of mapping iterations	1
Instrument type (MType)	AR1500ex
Firmware version	  8.29  27/10/09
Configuration version (CnfVer)	301
Parameter version (PrmVer)	301
PCB Number	*NOT_SET*
IP address	172.23.191.2
Software version	V5.8.2
Windows version	Windows XP 6.2
Instrument inertia	15,97 micro N.m.s^2
Auto increment run number	Yes
Prompt for file name at start of run	Yes
Auto save results file	Yes
Results file storage	Consecutive steps of same type to 1 file 
Temperature tolerance	0,2 C
Temperature duration	0:00:10 hh:mm:ss
Wait for temperature even if OK	Yes
Gap tolerance	4 micro m
Gap duration	0:00:02 hh:mm:ss
Override wait for gap	No
Velocity tolerance	0,1000 rad/s
Zero speed after pre-shear	Leave as is 
Zero normal force before run	No
Zero timer before run	Before pre-shear 
Non-equilibrium minimum velocity	3,000E-4 rad/s
Zero strain at the start of each flow step	Yes
Inertia correction	No
Collect negative shear rate data if stress is positive	Yes
Collect all points	No
Display flow point graph during run	Yes
Store flow point graph with results	Yes
Store images to the results for flow steps	No
Creep zero displacement	Yes
Store images to the results for creep steps	No
Standard creep image store frequency	10 s
Repeated creep image store frequency in repeats	10 
Display oscillation waveform graph during run	Yes
Store oscillation waveform graph with results	Yes
Display strain control tries during run	Yes
Store strain control tries with results	Yes
Store images to the results for oscillation steps	No
Stress relaxation zero displacement	Yes
Store images to the results for stress relaxation steps	No
Flow torque limit	10,00 micro N.m
Flow velocity limit	1,000E-3 rad/s
Oscillation torque limit	5,00 micro N.m
Oscillation displacement limit	1,00E-5 rad
Oscillation raw phase limit	170,0 degrees
Oscillation minimum normal force limit	0 N
Oscillation maximum normal force limit	0 N
Flow velocity tolerance	5,00 %
Oscillation torque tolerance	1,00 %
Oscillation displacement tolerance	5,00 %
Oscillation velocity tolerance	5,00 %
Temperature tolerance	1,0 C

Stepped flow step 1

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

-3,847E-3	9,693E-4	-3,968	9,9840	25,0	0
0,03298	2,150E-3	15,34	20,046	25,0	0
0,1158	4,639E-3	24,96	30,031	25,0	0
0,2761	9,999E-3	27,61	40,109	25,0	0

Stepped flow step 2

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,4037	9,998E-3	40,38	9,9370	25,0	0
0,6900	0,02154	32,03	19,968	25,0	0
1,204	0,04641	25,93	30,047	25,0	0
1,753	0,1000	17,53	40,078	25,0	0
1,562	0,1000	15,61	50,140	25,0	0

Stepped flow step 3

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

1,147	0,1000	11,47	9,9060	25,0	0
1,006	0,1585	6,348	20,031	25,0	0
0,8041	0,2512	3,201	30,171	25,0	0
0,6331	0,3981	1,590	40,265	25,0	0
0,5044	0,6310	0,7993	50,312	25,0	0
0,3935	0,9999	0,3935	60,421	25,0	0

Stepped flow step 4

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,3317	1,000	0,3317	9,9690	25,0	0
0,3021	1,333	0,2266	20,000	25,0	0
0,2830	1,778	0,1591	30,078	25,0	0
0,2667	2,371	0,1125	40,203	25,0	0
0,2600	3,162	0,08223	50,313	25,0	0
0,2577	4,217	0,06110	60,375	25,0	0
0,2294	5,624	0,04079	70,500	25,0	0
0,2195	7,499	0,02928	80,563	25,0	0
0,3022	10,00	0,03022	90,625	25,0	0
0,4912	13,34	0,03683	100,69	25,0	0
0,8470	17,78	0,04763	110,72	25,0	0
1,278	23,71	0,05389	121,05	25,0	0
1,924	31,62	0,06083	131,08	25,0	0
2,607	42,17	0,06183	141,17	25,0	0
4,072	56,23	0,07241	151,28	25,0	0
5,809	74,99	0,07747	161,36	25,0	0
8,294	100,0	0,08294	171,42	25,0	0

Temperature ramp step 1

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,3491	10,00	0,03491	9,0080	25,0	0
0,3456	10,00	0,03456	18,004	25,5	0
0,3428	10,00	0,03428	27,008	26,7	0
0,3374	10,00	0,03374	36,004	28,1	0
0,3337	10,00	0,03337	45,020	29,8	0
0,3294	10,00	0,03293	54,008	31,5	0
0,3254	10,00	0,03254	63,008	33,2	0
0,3219	10,00	0,03219	72,008	34,9	0
0,3189	10,00	0,03189	80,988	36,5	0
0,3206	10,00	0,03206	90,004	38,1	0
0,3208	10,00	0,03208	98,992	39,7	0
0,3205	10,00	0,03205	107,99	41,3	0
0,3230	10,00	0,03230	117,00	42,8	0
0,3244	10,00	0,03244	126,01	44,4	0
0,3225	10,00	0,03225	135,00	45,9	0
0,3210	10,00	0,03210	144,02	47,4	0
0,3240	10,00	0,03240	153,01	48,9	0
0,3247	10,00	0,03247	162,00	50,3	0
0,3214	10,00	0,03215	171,02	51,9	0
0,3233	10,00	0,03233	180,01	53,4	0
0,3257	10,00	0,03257	189,00	54,8	0
0,3258	10,00	0,03258	198,01	56,3	0
0,3265	10,00	0,03265	207,00	57,8	0
0,3172	10,00	0,03172	216,02	59,3	0
0,3164	10,00	0,03165	225,02	60,8	0
0,3185	10,00	0,03185	233,99	62,3	0
0,3189	10,00	0,03189	243,01	63,8	0
0,3236	10,00	0,03236	252,00	65,3	0
0,3266	10,00	0,03266	261,01	66,8	0
0,3330	10,00	0,03330	270,00	68,4	0
0,3442	10,00	0,03442	279,01	69,9	0
0,3648	10,00	0,03648	288,01	71,4	0
0,4071	10,00	0,04071	296,99	72,8	0
0,5118	9,999	0,05118	306,00	74,4	0
0,7893	9,999	0,07894	315,01	76,0	0
1,529	9,999	0,1529	324,00	77,5	0
2,754	9,999	0,2754	333,02	79,1	0
4,299	10,00	0,4299	342,01	80,6	0
6,569	9,999	0,6570	351,00	82,0	0
8,873	10,00	0,8874	360,00	83,3	0
10,81	10,00	1,081	369,00	84,7	0

Temperature ramp step 2

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

12,33	10,00	1,233	8,9920	86,6	0
12,71	10,00	1,271	18,008	88,8	0
14,18	9,999	1,418	26,992	90,0	0
14,84	10,00	1,484	35,992	90,6	0
14,81	10,00	1,481	45,000	91,0	0
14,83	10,00	1,483	54,004	91,0	0
14,46	10,00	1,446	62,988	91,0	0
14,14	9,999	1,414	71,992	90,8	0
13,89	10,00	1,389	80,992	90,7	0
13,69	10,00	1,369	90,004	90,6	0
13,54	10,00	1,354	98,992	90,5	0
13,35	10,00	1,335	108,00	90,3	0
13,17	10,00	1,317	117,00	90,3	0
13,07	10,00	1,307	125,98	90,2	0
12,89	10,00	1,289	135,00	90,1	0
12,77	10,00	1,277	143,99	90,1	0
12,62	10,00	1,262	153,00	90,1	0
12,49	10,00	1,249	161,98	90,0	0
12,38	10,00	1,238	171,00	90,0	0
12,28	10,00	1,228	180,00	90,0	0
12,19	9,999	1,219	188,98	90,0	0
12,02	10,00	1,202	197,99	90,0	0
11,96	9,999	1,196	207,00	90,0	0
11,82	10,00	1,182	216,00	90,0	0
11,73	10,00	1,173	224,98	90,0	0
11,65	10,00	1,165	234,01	90,0	0
11,52	10,00	1,152	243,00	90,0	0
11,42	10,00	1,142	252,00	90,0	0
11,35	9,999	1,135	261,00	90,0	0
11,25	10,00	1,125	270,00	90,0	0
11,15	10,00	1,115	278,99	90,0	0

Temperature ramp step 3

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

11,07	10,00	1,107	9,0120	90,0	0
10,97	10,00	1,097	18,004	89,4	0
10,78	10,00	1,078	27,000	86,2	0
10,61	9,999	1,061	36,008	85,4	0
10,54	10,00	1,054	45,004	84,8	0
10,47	10,00	1,047	53,992	82,9	0
10,39	10,00	1,039	63,016	81,3	0
10,35	10,00	1,035	71,996	80,4	0
10,38	10,00	1,038	81,008	78,2	0
10,36	10,00	1,036	90,016	76,8	0
10,42	10,00	1,042	99,004	75,9	0
10,46	10,00	1,046	108,01	73,3	0
10,49	10,00	1,049	117,01	72,6	0
10,62	10,00	1,062	126,00	70,8	0
10,71	10,00	1,071	135,00	69,1	0
10,76	10,00	1,076	144,00	68,3	0
10,94	10,00	1,094	152,98	66,0	0
11,03	10,00	1,103	162,00	65,2	0
11,19	10,00	1,119	170,99	62,9	0
11,32	10,00	1,133	180,00	61,9	0
11,55	10,00	1,155	188,99	60,3	0
11,73	9,999	1,173	197,99	58,5	0
11,92	10,00	1,193	207,00	57,6	0
12,19	10,00	1,219	216,01	55,4	0
12,37	9,999	1,237	225,00	54,5	0
12,72	10,00	1,272	234,00	52,6	0
12,95	10,00	1,295	243,01	51,2	0
13,31	10,00	1,331	252,00	49,9	0
13,70	10,00	1,370	260,99	48,0	0
14,08	10,00	1,408	270,01	46,9	0
14,43	9,999	1,443	279,00	45,0	0
14,94	10,00	1,494	288,00	43,8	0
15,28	10,00	1,528	297,00	42,2	0
15,76	9,999	1,576	306,00	40,7	0
16,22	10,00	1,622	314,99	39,2	0
16,64	10,00	1,664	324,00	37,7	0
17,01	9,999	1,701	333,00	36,3	0
17,51	10,00	1,751	341,99	34,7	0
17,96	10,00	1,797	351,00	33,2	0
18,55	10,00	1,855	360,00	31,9	0
19,19	9,999	1,919	368,99	30,3	0

Stepped flow step 5

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,1829	1,002E-3	182,6	9,9530	24,9	0
0,4203	2,154E-3	195,2	20,016	24,9	0
0,7626	4,640E-3	164,3	30,078	25,0	0
1,347	9,998E-3	134,8	40,157	25,0	0

Stepped flow step 6

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

1,645	9,999E-3	164,5	9,9690	24,9	0
2,299	0,02154	106,7	20,078	25,0	0
3,159	0,04642	68,05	30,203	25,1	0
4,168	0,1000	41,68	40,282	25,0	0
4,229	0,1000	42,29	50,375	24,9	0

Stepped flow step 7

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

4,280	0,1000	42,80	9,9680	25,0	0
5,067	0,1585	31,97	20,062	25,0	0
6,039	0,2512	24,04	30,093	24,9	0
7,229	0,3981	18,16	40,172	25,0	0
8,719	0,6310	13,82	50,203	25,0	0
10,48	1,000	10,48	60,281	25,0	0

Stepped flow step 8

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

10,13	1,000	10,13	9,9220	24,9	0
11,37	1,334	8,525	20,031	25,0	0
12,81	1,778	7,203	30,125	25,0	0
14,54	2,371	6,131	40,156	25,0	0
16,82	3,162	5,320	50,234	25,0	0
19,35	4,217	4,589	60,297	25,0	0
22,39	5,623	3,981	70,375	25,0	0
25,97	7,499	3,463	80,437	25,0	0
30,01	10,00	3,001	90,547	25,0	0
34,39	13,34	2,579	100,56	25,0	0
39,12	17,78	2,200	110,59	25,1	0
43,72	23,71	1,844	120,69	25,0	0
48,55	31,62	1,535	130,72	25,0	0
53,38	42,17	1,266	140,78	25,0	0
58,46	56,23	1,040	150,80	25,0	0
66,37	74,99	0,8850	160,89	25,0	0
67,23	100,0	0,6723	170,94	25,0	0

